Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply. Players may hold more than one non-FIFA nationality.
Litex Lovech, as A Group winners in the previous season, played against CSKA Sofia in the 2011 Bulgarian Supercup, who themselves won the Bulgarian Cup.
^Ludogorets Razgrad won the 2011–12 Bulgarian Cup competition but were qualified for 2012–13 UEFA Champions League via winning the league, hence their Europa League berth was awarded to the cup runners-up, Lokomotiv Plovdiv.
^The match was played at the Podgorica City Stadium in Podgorica, instead of Mogren regular stadium, the Stadion Lugovi in Budva, which did not meet UEFA requirements.