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Potassium bisulfate

Potassium bisulfate
One potassium cation and one hydrogensulfate anion
Ball-and-stick model of the component ions
Potassium bisulfate crystals on filter paper
Names
IUPAC name
Potassium hydrogen sulfate
Other names
Potassium acid sulfate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.028.722 Edit this at Wikidata
EC Number
  • 231-594-1
E number E515(ii) (acidity regulators, ...)
RTECS number
  • TS7200000
UNII
UN number 2509
  • InChI=1S/K.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1 ☒N
    Key: CHKVPAROMQMJNQ-UHFFFAOYSA-M ☒N
  • InChI=1/K.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1
    Key: CHKVPAROMQMJNQ-REWHXWOFAH
  • OS(=O)(=O)[O-].[K+]
Properties
KHSO4
Molar mass 136.169 g/mol
Appearance colorless solid
Odor odorless
Density 2.245 g/cm3
Melting point 197 °C (387 °F; 470 K)
Boiling point 300 °C (572 °F; 573 K) (decomposes to form potassium pyrosulfate and water)
36.6 g/100 mL (0 °C)
49 g/100 mL (20 °C)
121.6 g/100 mL (100 °C)
Solubility soluble in acetone, ethanol.
−49.8·10−6 cm3/mol
Thermochemistry
-1163.3 kJ/mol
Hazards
GHS labelling:
GHS05: CorrosiveGHS07: Exclamation mark
Danger
H314, H335
P260, P261, P264, P271, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P363, P403+P233, P405, P501
Lethal dose or concentration (LD, LC):
2340 mg*kg−1
Safety data sheet (SDS) External MSDS
Related compounds
Related compounds
 Potassium sulfate
Sodium bisulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium bisulfate (potassium bisulphate) is an inorganic compound with the chemical formula KHSO4 and is the potassium acid salt of sulfuric acid. It is a white, water-soluble solid.

Preparation

More than 1 million tons were produced in 1985 as the initial stage in the Mannheim process for producing potassium sulfate. The relevant conversion is the exothermic reaction of potassium chloride and sulfuric acid:[1][2]

KCl + H2SO4 → HCl + KHSO4

Potassium bisulfate is a by-product in the production of nitric acid from potassium nitrate and sulfuric acid:[3]

KNO3 + H2SO4 → KHSO4 + HNO3

Chemical properties

Thermal decomposition of potassium bisulfate forms potassium pyrosulfate:[1]

2 KHSO4 → K2S2O7 + H2O

Above 600 °C potassium pyrosulfate converts to potassium sulfate and sulfur trioxide:[4]

K2S2O7 → K2SO4 + SO3

Uses

Potassium bisulfate is commonly used to prepare potassium bitartrate for winemaking.[5] Potassium bisulfate is also used as a disintegrating agent in analytical chemistry or as a precursor to prepare potassium persulfate, a powerful oxidizing agent.[6]

Occurrence

Mercallite, the mineralogical form of potassium bisulfate, occurs very rarely.[7] Misenite is another more complex form of potassium bisulfate with the formula K8H6(SO4)7.

References

  1. ^ a b Washington Wiley, Harvey (1895). Principles and Practice of Agricultural Analysis: Fertilizers. Easton, PA.: Chemical Publishing Co. p. 218. Retrieved 31 December 2015. Potassium disulfate.
  2. ^ H. Schultz; G. Bauer; E. Schachl; F. Hagedorn; P. Schmittinger (2005). "Potassium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a22_039. ISBN 978-3-527-30673-2.
  3. ^ Pradyot, Patnaik (2003). Handbook of Inorganic Chemicals. New York: McGraw-Hill. p. 636. ISBN 978-0-07-049439-8.
  4. ^ Iredelle Dillard Hinds, John (1908). Inorganic Chemistry: With the Elements of Physical and Theoretical Chemistry. New York: John Wiley & Sons. p. 547. Retrieved 31 December 2015. Potassium disulfate.
  5. ^ Weisblatt, Jayne; Montney, Charles B. (2006). Chemical Compounds. ISBN 978-1-4144-0453-0.
  6. ^ Brauer, Georg (1963). Handbook of Preparative Inorganic Chemistry Vol. 1, 2nd Ed. New York: Academic Press. p. 392. ISBN 978-0-12-126601-1.
  7. ^ "Mercallite: Mineral information, data and localities". mindat.org. Retrieved 2019-05-08.
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