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Azuleno

Azuleno
Formula kimikoaC10H8
SMILES kanonikoa2D eredua
MolView3D eredua
Konposizioakarbono
Motahidrokarburo aromatiko polizikliko, simple aromatic ring (en) Itzuli, Konposatu bizikliko eta polar molecule (en) Itzuli
Ezaugarriak
Momentu dipolarra0,8 D
Fusio-puntua100 ℃
99 ℃
Fusio-entalpia0,8 D
Masa molekularra128,063 Da
Erabilera
Rolaantiinflamatorio ez esteroideo
Identifikatzaileak
InChlKeyCUFNKYGDVFVPHO-UHFFFAOYSA-N
CAS zenbakia275-51-4
ChemSpider8876
PubChem9231
Reaxys969517
Gmelin31249
ChEBI102129
ChEMBLCHEMBL3272628
RTECS zenbakiaCO4570000
DSSTox zenbakiaCO4570000
EC zenbakia205-993-6
ECHA100.005.449
CosIng74540
MeSHC005525
Human Metabolome DatabaseHMDB0248822
KNApSAcKC00042269
UNII82R6M9MGLP
KEGGC13392

Azulenoa konposatu organikoa da C10H8 formula duena, hidrokarburo aromatiko poliziklikoen klasekoa. Solido kristalino azula da eta horri zor dio izena. Naftalenoaren isomeroa da[1].

Bere deribatuek ere kolore urdina dute eta hainbat landaretan aurkitzen dira. Adibidez, kamamilak kamazuleno du. Kolore urdineko tinduak kamamilaren destilazioz eskuratu izan dira XV. mendetik hona.

Produkzioa eta sintesia

Azulenoa hainbat landareren olioak destilatuz lor daiteke; hala nola, milorria (Achillea millefolium), mendafina (Mentha X piperita L.) eta lasturrina (Acorus calamus)[2].

Azulenoak duen interes teorikoa medio, hainbat bide sintetiko garatu dira. Horietako interesgarrienetako bat zikloheptatrienoaren eta dikloro zetenaren erreakzioarekin abiatzen da[3].

Azulenesynthesis

Erreferentziak

  1. (Ingelesez) PubChem. «Azulene» pubchem.ncbi.nlm.nih.gov (kontsulta data: 2024-09-23).
  2. (Ingelesez) Teufel,, Dawn R.. (1999). Final Report on the Safety Assessment of Azulene. International Journal of Toxicology, 18(S3), 27-32 or..
  3. (Ingelesez) Carret, Sébastien; Blanc, Aurélien; Coquerel, Yoann; Berthod, Mikaël; Greene, Andrew E.; Deprés, Jean‐Pierre. (2005-08-12). «Approach to the Blues: A Highly Flexible Route to the Azulenes» Angewandte Chemie International Edition 44 (32): 5130–5133.  doi:10.1002/anie.200501276. ISSN 1433-7851. (kontsulta data: 2024-09-23).

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