Stannane

Stannane
Ball-and-stick model of the stannane molecule	Space-filling model of the stannane molecule Tin, Sn Hydrogen, H
Names
	IUPAC name Stannane
	Other names tin tetrahydride; tin hydride
Identifiers
CAS Number	2406-52-2 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:30419 ;
ChemSpider	109776 ;
PubChem CID	123161;
CompTox Dashboard (EPA)	DTXSID50894052 ;
	InChI InChI=1S/Sn.4H Key: KXCAEQNNTZANTK-UHFFFAOYSA-N ; InChI=1/Sn.4H/rH4Sn/h1H4 Key: KXCAEQNNTZANTK-GVMKXMNPAM;
	SMILES [Sn];
Properties
Chemical formula	SnH4
Molar mass	122.71 g/mol
Appearance	colourless gas
Density	5.4 g/L, gas
Melting point	−146 °C (−231 °F; 127 K)
Boiling point	−52 °C (−62 °F; 221 K)
Structure
Molecular shape	Tetrahedral
Dipole moment	0 D
Thermochemistry
Heat capacity (C)	1.262 kJ/(kg·K)
Std enthalpy of; formation (ΔfH⦵298)	162.8 kJ/mol
Enthalpy of vaporization (ΔfHvap)	19.049 kJ/mol
Related compounds
Related organotins	tributylstannane (Bu3SnH)
Related compounds	Methane; Silane; Germane; Plumbane
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Stannane /ˈstæneɪn/ or tin hydride is an inorganic compound with the chemical formula Sn H₄. It is a colourless gas and the tin analogue of methane. Stannane can be prepared by the reaction of SnCl₄ and Li[AlH₄].^[1]

SnCl₄ + Li[AlH₄] → SnH₄ + LiCl + AlCl₃

Stannane decomposes slowly at room temperature to give metallic tin and hydrogen and ignites on contact with air.^[1]

Variants of stannane can be found as a highly toxic, gaseous, inorganic metal hydrides and group 14 hydrides.

References

^ ^a ^b Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.