Azirina
| Azirina | |
|---|---|
 | |
| Formula kimikoa | C2H3N |
| SMILES kanonikoa | 2D eredua |
| MolView | 3D eredua |
| Konposizioa | Nitrogeno eta karbono |
| Mota | azirine (en)  |
| Masa molekularra | 41,027 Da |
| Identifikatzaileak | |
| InChlKey | NTJMGOWFGQXUDY-UHFFFAOYSA-N |
| CAS zenbakia | 157-16-4 |
| ChemSpider | 119750 |
| PubChem | 135972 |
| Reaxys | 1633516 |
| Gmelin | 30971 |
Azirina hiru begiko heteroziklo asegabea da begietako batean nitrogeno-atomoa duena. Azirinak bi isomero dauzka: batean lotura bikoitza karbono-atomoen artean eratzen da eta bestean karbonoaren eta nitrogenoaren artean. Lehenari 1H-azirina esaten zaio eta bigarrenari 2H-azirina. 1H-azirina ez egonkorra eta errez bihurtzen da bere tautomero 2H-azirina[1]
Azirinaren deribatu ordezkatuek azirinen familia osatzen dute. Aziridinak bere analogo asegabeak dira. Azirinak oso erreaktiboak dira, baina familia honetako disidazirina konposatua aurkitu da Dysidea fragilis belakian[2].
Sintesia
2H-azirina normalean binilo-aziden termolisiz sintetizatzen da. Erreakzioaren bitarteko produktu gisa nitrenoa eratzen da. Halaber, 2H-azirina azidirinaren oxidazioz lor daiteke[3].
Erreferentziak
- ↑ (Ingelesez) Melo, Teresa M. V. D. Pinho e; Gonsalves, Antonio M. d'A Rocha. «Exploiting 2-Halo-2H-Azirine Chemistry» Current Organic Synthesis 1 (3): 275–292. (kontsulta data: 2022-11-13).
- ↑ (Ingelesez) «(R)-Dysidazirine» American Chemical Society (kontsulta data: 2022-11-13).
- ↑ (Ingelesez) Ochoa de Retana, Ana María; Martinez de Marigorta, Eduardo; de los Santos, Juan Manuel & Palacios, Francisco. (2001). 2H-Azirines as Synthetic Tools in Organic Chemistry. European Journal of Organic Chemistry, 13, 2401-2414 or..
Kanpo estekak
Datuak: Q424273
Multimedia: 2H-Azirine / Q424273
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