Oxepina
| Oxepina | |
|---|---|
 | |
| Formula kimikoa | C6H6O |
| SMILES kanonikoa | 2D eredua |
| MolView | 3D eredua |
| Konposizioa | oxigeno, karbono eta hidrogeno |
| Mota | oxacycle (en)  |
| Tautomeroa | benzene oxide (en) |
| Masa molekularra | 94,041865 Da |
| Identifikatzaileak | |
| InChlKey | ATYBXHSAIOKLMG-UHFFFAOYSA-N |
| CAS zenbakia | 291-70-3 |
| ChemSpider | 4953942 |
| PubChem | 6451477 |
| Gmelin | 230029 |
| Human Metabolome Database | HMDB0255979 |
| UNII | CVP5X85XX5 |
Oxepina konposatu organiko ziklikoa da zazpi kate-begiz osatutakoa eta oxigeno bat eta hiru lotura bikoitz dituena[1]. Ez da konposatu aromatikoa eta eter enoliko ziklikotzat jo daiteke.
Oxepina oreka tautomerikoan dago bentzeno oxidoarekin. Oreka alde batera edo bestera desplazatuko da zikloan dauden ordezkatzaileen arabera[2].
Sintesia
Oxepina sintezatzeko 4,5-dibromoziklohexanoaren epoxidoa base batekin tratatzen da, deshidrohalogenazioa pasatzen delarik. Basea DBU izan daiteke[3].
Erreferentziak
- ↑ (Ingelesez) PubChem. «Oxepin» pubchem.ncbi.nlm.nih.gov (kontsulta data: 2021-04-24).
- ↑ (Ingelesez) Vogel, E.; Günther, H.. (1967). «Benzene Oxide-Oxepin Valence Tautomerism» Angewandte Chemie International Edition in English 6 (5): 385–401. doi:. ISSN 1521-3773. (kontsulta data: 2021-04-24).
- ↑ (Ingelesez) Gillard, James R.; Newlands, Michael J.; Bridson, John N.; Burnell, D. Jean. (2011-02-05). «π-Facial stereoselectivity in the Diels–Alder reactions of benzene oxides» Canadian Journal of Chemistry doi:. (kontsulta data: 2021-04-24).
Kanpo estekak
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